2015年4月28日 更新
旧分析化学研究室


姫路工業大学分析化学研究室

旧分析化学研究室の歴史



Refereed Paper
01) 重松恒信, 松井正和, 藤野治, 三野将司, 永廣徹, 炭素チューブ原子化装置による海水および貝中の銅の原子吸光分析, 日本化学会誌, 1328-1331 (1975).
02) K. Uesugi, T. Nagahiro, and M. Miyawaki, A highly sensitive spectrophotometric determination of uranium with chromal blue G in the presence of cetyltrimethylammonium chloride, Anal. Chim. Acta, 148, 315-320 (1983).
03) T. Nagahiro, M. Satake, B. K. Puri, and J-L. Lin, Spectrophotometric determination of Iron (II) by extractionof its ion associated complex with 3-(4- phenyl-2-pyridyl)-5,6-diphenyl-1,2,4-triazine and tetra-phenylborate into molten naphthalene, Mikrochim. Acta, 85-93 (1984).
04) M. Satake, T. Nagahiro, and B. K. Puri, Solid-liquid separation after liquid liquid extraction spectrophotometric determination of iron (II) by extractionof its ternary complex with 2,2-dipyridyl and tetraphenylborateinto molten naphthalene, Analyst, 109, 31-34 (1984).
05) T. Nagahiro, M. Satake, J-L. Lin, and B. K. Puri, Spectrophotometric determination of cobalt after separation by adsorption of its ternary complex with 4-(p-methoxyphenyl-2,2: 6,2-terpyridine and tetraphenylborate on to microcrystalline naphthalene, Analyst, 109, 163-165 (1984).
06) T. Nagahiro, Jenn-Lin, B. K. Puri, and M. Satake, Spectrophotometric determination of cobalt after extraction of its 4'-(p- Methoxyphenyl)-2,2,6',2”-terpyridine complex with tetra phenylborate anion into molten naphthalene, Chim. Acta Turc., 12, 423-430 (1984).
07) T. Nagahiro, B. K. Puri, M. Katyal, and M. Satake, Determination of nickel by flame atomic absorption spectrophotometry after separation by adsorption of its Ni oxide complexon microcrystalline naphthalene, Talanta, 31, 1008-1009 (1984).
08) T. Nagahiro, K. Uesugi, M. C. Mehra, and M. Satake, Specrophotometric determination of iron (II) after separation by adsorption of its complex with 3-(4-Phenyl-2-pyridyl)-5, 6-diphenyl-1,2,4-triazine and tetraphenylborate on microcrystalline naphthalene, Talanta, 31, 1112-1114 (1984).
09) M. C. Mehra, M. Satake, T. Nagahiro, A. K. Singh, and M. Katyal, Spectrophotometric determination of iron with neotetrazolium chloride, Acta Ciencia Indica, XIC, 81-82 (1985).
10) K. Uesugi, M. Miyawaki, and T. Nagahiro, Copper (II)-cetyltrimethylammonium chloride-chromal blue G ternary complex and its application to the spectrophotometric determination of copper (II), Microchem. J., 32, 332-337 (1985).
11) T. Nagahiro, K. Uesugi, and M. Satake, Spectrophotometric determination of Fe (II) by extraction of its ion-associated complex with 3-(2- Pyridyl)-5,6-diphenyl 1,2,4-triazine and tetraphenylborate anion into molten naphthalene, Anal. Sci., 1, 359-362 (1985).
12) A. Wasey, B. K. Puri, M. Satake, and T. Nagahiro, Spectrophotometric determination of iron (II) with phenanthrenequinone monoximein alloys, beers, wines, environmental samples and human hairs, Chim. Acta Turc., 13, 481-490 (1985).
13) T. Nagahiro, K. Uesugi, M. Satake, and B. K. Puri, Atomic absorption spectrophotometric determination of copper (I) after extraction of its ternary complex with 3-(4-phenyl-2-pyridyl)-5,6-diphenyl 1,2,4-triazine and tetraphenylborate into molten naphthalene, Bull. Chem. Soc. Jpn., 58, 1115-1118 (1985).
14) T. Nagahiro, M. Satake, and B. K. Puri, Atomic absorption spectrophotometric determination of copper (I) after extraction of its 2,4,6-tri(2-pyridyl)-1,3,5-triazine tetraphenylborate ion-associated complex into molten naphthalene, Zh. Anal. Khim., 40, 1601-1605 (1985).
15) M. Satake, M. C. Mehra, T. Nagahiro, and M. Katyal, Microanalysis of zinc by atomic absorption after its solid phase extraction on microcrystalline naphthalene, Oriental J. Chem., 2, 83 (1986).
16) T. Nagahiro, M. Satake, and B. K. Puri, Atomic absorption spectrophotometric determination of copper (I): extraction as 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine tetraphenylborate ternary complexinto molten naphthalene, Indian J. Chem., 25A, 99-100 (1986).
17) M. C. Mehra, T. Nagahiro, and M. Satake, Spectrophotometric determination of cobalt after separation by adsorption of its ternary complex with 3-(2-pyridyl)-5,6-diphenyl-1,2,4-triazine and tetraphenylborate on microcrystalline naphthalene, Microchem. J., 33, 198-203 (1986).
18) T. Nagahiro, K. Uesugi, and M. Satake, Chromatographic preconcentration of iron (III) with 1,10-phenanthroline and tetraphenylborate supported on naphthalene, Analyst, 111, 1389-1391 (1986).
19) T. Nagahiro, K. Uesugi, and M. Satake, Determination of copper (II) by flame atomic absorption spectrophotometry after separation by adsorption of its 1,4-dihydroxyanthraquinone complex onto microcrystalline naphthalene, Analusis, 16, 120-123 (1986).
20) 藤野治, 松井正和, 永廣徹, 中口譲, 平木敬三, グラファイト炉-原子吸光分析法および放射化分析法によるハマグリ貝殻中のマンガンの定量と分布, 日本化学会誌, 153-156 (1988).
21) T. Nagahiro and K. Uesugi, Spectrophotometric determination of iron in sea waters and common salts by a column method using 2,2'-dipyridyl-tetraphenylborate-naphthalene as an adsorbent, Bull. Soc. Sea Water Sci. Jpn., 42, 182-185 (1988).
22) T. Nagahiro and K. Uesugi, Preconcentration of copper by a column method using neocuproine and tetraphenylborate supported on naphthalene, Zh. Anal. Khim., 44, 2191-2194 (1989).
23) 西岡洋, 梅本諭, 深田哲右, DDTC錯体共沈法を用いる水中のセレンの蛍光X線分析, 環境技術, 18, 40 (1989).
24) T. Kumagai, M. Matsui, Coprecipitation of manganese with calcite and aragonite between 15℃ to 50℃, Radioisotopes, 38, 1-6 (1989).
25) T. Kumagai and K. Uesugi, Cation exchange studies of cadmium chloride, bromide and iodide complexes in aqueous acetone solution, 日本イオン交換学会誌, 1, 16 (1990).
26) 上杉勝彌, 森江勉, 熊谷哲, 永廣徹, 3,5-ジブロモサリチルアルデヒド-2-ベンゾチアゾリルヒドラゾンを用いる食塩中のバナジウムの溶媒抽出-炭素炉原子吸光分析, 日本海水学会誌, 44, 262-266 (1990).
27) A. Kumar, R. K. Shukla, R. S. Agarwal, M. Satake, and T. Nagahiro, Spectrophotometric determination of osmium after separation by adsorption of its ternary complex with 3-(4-phenyl-2-pyridyl)-5,6-diphenyl1,2,4-triazine and tetraphenylborate anion with microcrystalline naphthalene, Chim. Acta Turc., 18, 477-482 (1990).
28) K. Uesugi and M. Miyawaki, A sensitive spectrophotometric method for the determination of palladium with eriochrome azurol G and cetyltrimethylammonium choloride, Microchem. J., 41, 78 (1990).
29) 西岡洋, 熊谷哲, 永廣徹, 上杉勝弥, エリオクロームアズロールBを用いる天然水中のマグネシウムのフローインジェクション分析, 日本海水学会誌, 45, 78-82 (1991).
30) 上杉勝弥, 三木亮太郎, 西岡 洋, 熊谷哲, 永廣徹, 3,5-ジクロロサリチルアルデヒド-4-フェニル-3-チオセミカルバゾンを用いる海水および食塩中の銅の溶媒抽出-炭素炉原子吸光分析, 日本海水学会誌, 45, 188-192 (1991).
31) K. Uesugi, T. Nagahiro, T. Kumagai, and H. Nishioka, Extraction-spectrophotometric determination of palladium (II) with 2-hydroxy-1-naphthaldehyde-4-phenyl-3-thiosemicarbazone, Oriental J. Chem., 7, 176-180 (1991).
32) K. Uesugi, T. Nagahiro, T. Kumagai, and H. Nishioka, Extraction-spectrophotometric determination of palladium (II) with 5-bromosalicylaldehyde-4-phenyl-3-thiosemicarbazone, Chim. Acta Turc., 19, 245-250 (1991).
33) 熊谷哲, 西岡洋, 佐井規雄, 上杉勝弥, Cによるフローインジェクション分析用化学計測プログラム, 化学PC研究会誌, 13, 3-36 (1991).
34) 上杉勝弥, 末広省吾, 西岡洋, 熊谷哲, 永廣徹, 5-ニトロサリチルアルデヒド-4-フェニル-3-チオセミカルバゾンを用いる海水および食塩中のニッケルの溶媒抽出-原子吸光分析, 日本海水学会誌, 46, 22-26 (1992).
35) 西岡洋, 佐井規雄, 熊谷哲, 永廣徹, 上杉勝弥, アゾメチンHを用いる海水および製塩試料中のホウ素のフロ?インジエクション分析, 日本海水学会誌, 46, 391-396 (1992).
36) M. Satake, T. Nagahiro, and B. K. Puri, Column preconcentration of iron (III) with an ion pair of 1,2-dihydroxybenzene 3,5-disulfonate and benzyldimethyltetra-decylammonium ion supported on naphthalene using flame atomic absorption spectrometry, J. Anal. At. Spectrom., 7,183-186 (1992).
37) M. Satake, T. Nagahiro, and B. K. Puri, Column preconcentration of titanium in aluminium and zinc alloys with oxalic acid-ascorbic acid and the ion-pair of sodium1,2-dihydroxybenzene3,5-disulphonic acid and tetradecyldimethylbenzylammonium chloride supported on naphthalene using spectrometry, Talanta, 39, 1349-1354 (1992).
38) T. Kumagai and M. Matsui, Coprecipitation of cadmium with calcium carbonate from aqueous solutions at 15 to 50℃, Radioisotopes, 41, 57-63 (1992).
39) M. Satake, T. Nagahiro, and B. K. Puri, Column preconcentration of cobalt in alloys and pepperbush using 2-(5-bromo2-pyridylazo)-5-diethylaminophenol and ammonium tetraphenylborate adsorbent supported on naphthalene with subsequent determination ssing atomic absorption spectrometry, Analyst, 118, 85-88 (1993).
40) T. Nagahiro, K. Uesugi, and M. Satake, Column preconcentration of cobalt using 4-(5-bromo-2-pyridylazo)-1,3-diaminobenzene and ammonium tetraphenylborate supported on naphthalene and its analysis using atomic absorption spectrometry, Asian J. Chem., 5, 743-748 (1993).
41) 西岡洋, 熊谷哲, 永廣徹, 上杉勝弥, Reimer-Tiemann反応を用いる水中のクロロホルムのフロ?インジェクション分析, 環境技術, 22, 599-603 (1993).
42) K. Uesugi, H. Nishioka, T. Kumagai, and T. Nagahiro, Extraction-spectrophotometric determination of cadmium (II) with picolinaldehyde-4-phenyl-3-thiosemicarbazone, Oriental J. Chem., 9, 268-273 (1993).
43) T. Nagahiro, K. Uesugi, and M. Satake, Column precooncetration of cobalt using 4-(5-bromo-2-pyridylazo)-1,3-diaminobenzene and ammonium tetraphenylborate supported on naphtthanele and its analysis using atomic absorption spectroscopy, Asian J. Chem., 5, 743 (1993).
44) M. Satake, T. Nagahiro, and B. K. Puri, Column preconcentration of cobalt alloys and pepperbush using 2-(5-bromo-2-pyridylazo)-5-diethylaminophenol and ammonium tetraphenylborate adsorbent supported on naphthalene with subsequent determination using atomic absorption spectroscopy, Analyst, 118, 85 (1993).
45) 西岡洋, 佐井規雄, 熊谷哲, 永廣徹, 上杉勝弥, アルフッソンを用いる海水中のフッ化物イオンのフローイジェクション分析, 日本海水学会誌, 48, 10-14 (1994).
46) T. Nagahiro, K. Uesugi, and M. Satake, Column preconcentration of zinc using 4-(2-pyridylazo)resorcinol and the ion-pair material of trioctyl-methylammonium and bromate supported on biphenyl and its analysis using atomic absorption spectrometry, Oriental J. Chem., 10, 1-4 (1994).
47) K. Uesugi, L. J. Sikh, H. Nishioka, T. Kumagai, and T. Nagahiro, Extraction spectrophotometric determination of palladium with 3-thiophenaldehyde-4-phenyl-3-thiosemicarbazone, Microchem. J., 50, 88-93 (1994).
48) S. A. Wasay, S. Tokunaga, M. J. Haron, A. Uchiumi, T. Nagahiro, and B. K. Puri, Removal of Cu, Ir, Pd and Os ions in the form of chelates from wastewaters by naphthalene, J. Environ. Sci. Health, A29, 1817-1828 (1994).
49) J-S. Lee, K. Uesugi, T. Nagahiro, T. Kumagai, and H. Nishioka, Extraction spectrophotometric determination of mercury (II) using 2-hydroxy-1-naphthaldehyde-4-phenyl-3-semicarbazone as a selective reagent, Oriental J. Chem., 10, 181-186 (1994).
50) T. Nagahiro, M. Satake, and B. K. Puri, Column preconcentration of iron (III) using protocatechuic acid and the ion-pairof tetradecyldimethylbenzylammonium and iodide supported on naphthalene and its analysis using atomic absorption spectrometry, Chimica Acta Turc., 23, 125-129 (1995).
51) T. Nagahiro, G. F. Wang, and M. Satake, Column preconcentration of aluminum and copper (II) in alloys, biological samples, and environmental samples with alizarin red S and cetyltrimethylammonium perchlorate adsorbent supported on naphthalene using spectrometry, Microchem. J., 52, 247-256 (1995).
52) J-S. Lee, K. Uesugi, T. Nagahiro, W-H. Choi, K-T. Kim, and S-Y. Choi, Determination of gold by flame atomic absorption spectrophotometry using a new chelating agent, J. Korean Soc. Anal. Sci., 8, 391-396 (1995).
53) 西岡洋, 熊谷哲, 永廣徹, 3-ヒドロキシ-4´-エトキシフラボンを用いるアンチモン(III)のフローインジエクション分析, 分析化学, 45, 415-419 (1996).
54) 西岡洋, 岡田泰史, 熊谷哲, 永広徹, 上杉勝弥, 4,5-ジメチル-o-フェニレンジアミンを用いるセレンのフローインジェクション分析, 環境技術, 25, 285-288 (1996).
55) J-S. Lee, K. Uesugi, T. Nagahiro, W-H. Choi, and D-H. Kim, Determination of zinc in sea waters by flame atomic absorption spectrophotometry after solvent extraction using a new-chelating agent, Bull. Soc. Sea Water Sci. Jpn., 50, 344-348 (1996).
56) 山口茂六, 熊谷哲, 西岡洋, 多変量回帰分析法による数株多環芳香族炭化水素の同時定量, J. Chem. Software, 3, 65-72 (1996).
57) 西岡洋, 熊谷哲, 永広徹, チモールを用いるアンモニウムイオンのフローインジエクション分析, 環境技術, 26, 304-307 (1997).
58) 加藤康伸, 熊谷哲, 山口茂六, 西岡洋, 紫外可視吸収スペクトル/PLS法による化学的酸素要求量の予測, 分析化学, 48, 225 (1999).
59) T. Nagahiro and H. Nishioka, Spectrophotometric determination of ruthenium by a column method using 1,10-phenanthroline and ammonium tetraphenylborate supported on microcrystalline naphthalene, Oriental J. Chem., 15, 399 (1999).
60) 西岡洋, 永廣徹, 熊谷哲, 加藤康伸, 化学処理した茶葉を用いる水中の金属イオンの捕集能についての検討, 環境技術, 29, 788-792 (2000).
61) M. Mocerino, K. Mishima, H. Nishioka, A. Yonda, and M. Ouchi, Solvent extraction of metal picrates with calix[4]arene derivatives, Anal. Sci., 17, pi1223-1224 (2001).
62) 加藤康伸, 熊谷哲, 西岡洋, 杉江他曾宏, 播磨灘におけるノニフェノールの分析, 水環境学会誌, 25, 170-174 (2002).
63) H. Nishioka and T. Nagahiro, Flow injection analysis for alminium using 3-hydroxy-4’-chloroflavone, Dev. Chem. Eng. Mineral Process., 11, 437-444 (2003).
64) Y. Jing, K. Maenaka, H. Nishioka, S. Ioku, T. Fujita, and Y. Takayama, Quantitative analysis and influence of CO2 absorbed in TMAH solution for silicon etching, IEEJ Trans. SM, 123, 79-84 (2003).



Proceedings
01)H. Nishioka, R. Miki, and K. Uesugi, Extraction-spectrophotometric determination of copper (II) with triophenealdehyde-4-phenyl-3-thiosemicarbazone, Proceedings of the International Solvent Extraction Conference, 1990, 95 (1990).
02)H. Nishioka, R. Miki, and K. Uesugi, Extraction-spectrophotometric determination of copper(II) with thiophenealdehyde-4-phenyl-3-thiosemicarbazone, Proceedings of the International Solvent Extraction Conference, Process Metallurgy, 7A part A, 463 (1992).
03) T. Nagahiro, K. Uesugi, M. Satake, and B. K. Puri, Column preconcentration of vanadium, niobium and molybdenum using the ion-pair material of tiron and tetradecyldimethylbenzylammonium supported on naphthalene and their analysis using spectrometry, Proceedings of the 3rd International Symposium on Analytical Chemistry in the Exploration, Mining, and Processing of Materials, 131 (1992).
04) T. Nagahiro, K. Uesugi, and M. Satake, Column preconcentration of cobalt in alloys, pepperbush and pond sediment samples with 4-(5-bromo-2-pyridylazo)-1,3-diaminobenzene and ammonium tetraphenylborate supported on naphthalene, Proceedings of the International Conference on Analytical Chemistry Including Spectroscopy Across the Spectrum, Reading, U. K., Analytical Proceedings, 29, 357 (1992).
05) M. Satake, T. Nagahiro, and B. K. Puri, Column preconcentration of aluminum and copper in biological samples with alizarin red S and cetyltrimethylammonium-perchlirate adsorbent supported on naphthalene, Proceedins of the International Conference on Analytical Chemistry Including Spectroscopy Across the Spectrum, Reading, U. K., Analytical Proceedings, 29, 357 (1992).
06) J-S. Lee, K. Uesugi, and T. Nagahiro, Studies in Extraction of Metals with 4-Phenyl-3-thiosemicarbazonopicolinaldehyde, Analytical Proceedings, 32, 65-66 (1995).



紀要
01) 永廣徹, 上杉勝弥, 石原良雄, 村上敏治, 吸光光度法による貝肉および貝殻中のクロムの定量, 姫路工業大学研究報告, 21A, 95-101 (1968).
02) 永廣徹, 上杉勝弥, 石原良雄, 村上敏治, 吸光光度法による貝肉および貝がら中のニッケルの定量, 姫路工業大学研究報告, 22A, 92-96 (1969).
03) 永廣徹, 上杉勝弥, 石原良雄, 村上敏治, 原子吸光法による貝肉および貝がら中のカドミウムの定量, 姫路工業大学研究報告, 24A, 114-121 (1971).
04) T. Nagahiro, O. Fujino, M. Matsui, and T. Shigematsu, Determination of cadmium in individual organs and divided shells of sea water clam by atomic absorption spectrometry witha carbon tube atomizer, Bull. Inst. Chem. Res. Kyoto Univ., 56, 274-279 (1978).
05) K. Uesugi, T. Nagahiro, T. Kumagai, and S. Yamaguchi, Extraction spectrophotometric determination of copper with 3-methoxysalicylaldoxime, 姫路工業大学研究報告, 39A, 16-22 (1986).
06) T. Nagahiro, T. Kumagai, and K. Uesugi, Spectrophotometric determination of palladium (II) by extraction with 3,5-dibromosalicylaldehyde-4-phenyl-3-thiosemicarbazone, 姫路工業大学研究報告, 41A, 11-17 (1988).
07) T. Kumagai, T. Nagahiro Y. Ishihara, K. Uesugi, and S. Yamaguchi, Extraction-spectrophotometric determination of copper with 2-hydroxy1-naphthaldehyde-4-phenyl-3-thiosemicarbazone, 姫路工業大学研究報告, 41A, 18-23 (1988).
08) 永廣徹, 三木亮太郎, 熊谷哲, 西岡洋, 上杉勝弥, 3,5-ジクロロサリチルアルデヒド-4-フェニル-3-チオセミカルバゾンを用いる銅(II)の抽出吸光光度定量, 姫路工業大学研究報告, 42A, 1-7 (1989).
09) T. Kumagai, T. Morie, T. Nagahiro, K. Uesugi, and T. Ohara, Extraction spectrophotometric determination of vanadium (V) with 3,5-dichlorosalicylaldehyde-2-benzothiazolylhydrazone, 姫路工業大学研究報告, 42A, 8-14 (1989).
10) T. Nagahiro and K. Uesugi, Spectrophotometric determination of ruthenium after separation by extraction of its ternary complexwith 1,10-phenanthroline and tetraphenylborate anion into melted naphthalene, 姫路工業大学工学部研究報告, 43, 18-22 (1990).
11) H. Nishioka, S. Suehiro, T. Kumagai, T. Nagahiro, and K. Uesugi, Extraction spectrophotometric determination of vanadium (V) with picolinealdehyde-benzothiazolyl-hydrazone, 姫路工業大学工学部研究報告, 44, 14-19 (1991).
12) S. Yamaguchi and K. Uesugi, Extraction-spectrophotometric determination of manganese (II) with 2-hydroxy-1-naphthaldoxime, 姫路工業大学工学部研究報告, 44, 20 (1991).
13) T. Kumagai and K. Uesugi, Formation constants of cadmium chloride, bromide and iodide in ethylene glycol, 姫路工業大学工学部研究報告, 44, 9 (1991).
14) K. Uesugi,T. Kusuda, H. Nishioka, T. Kumagai, and T. Nagahiro, Extractive-spectrophotometric determination of micro amounts of copper with picolinealdehyde-4-phenyl-3-thiosemicarbazone, 姫路工業大学工学部研究報告, 45, 1-7 (1992).
15) S. Yamaguchi, K. Uesugi, and T. Kumagai, Extraction-spectrophotometric determination of cobalt with 5-nitrosalicylaldehyde-4-phenyl-3-thiosemicarbazone, 姫路工業大学工学部研究報告, 45, 8 (1992).
16) T. Kumagai, S. Yamaguchi, and K. Uesugi, Formation constants of lead chloride in aqueous ethylene glycol solutions, 姫路工業大学工学部研究報告, 46, 1 (1993).
17) M. Yamamoto, K. Uesugi, H. Nishioka, T. Kumagai, and T. Nagahiro, Highly sensitive method of extraction spectrophotometric determination of copper with p-dimethylaminobenzaldehyde-benzothiazolyl- hydrazone, 姫路工業大学工学部研究報告, 47, 1-9 (1994).
18) 松尾孝司, 上杉勝弥, 西岡洋, 熊谷哲, 永廣徹, 5-フェニルサリチルアルデヒド-4-フェニル-3-チオセミカルバゾンを用いるニッケル及びカドミウムの溶媒抽出-原子吸光分析, 姫路工業大学工学部研究報告, 47, 10-17 (1994).