Complete Crystallization Phase Diagram for manganese and magnesium sulphates mixtures in three aqueous alcohol solutions

Kouji Maeda Parviz Safaeefar Ha-Ming Ang Hidetoshi Kuramochi Yusuke Asakuma Keisuke Fukui Moses O.Tade
8th International Conference on Separation Science and Technology, ICSST08 (2008), in Karuizawa, Japan (2008)

The crystallization phase diagrams for the MnSO4.H2O, MgSO4.7H2O solute in three different alcoholic aqueous solution (methanol, ethanol and 2-propanol) were calculated by the ion specific electrolyte NRTL model. We have discussed the salting-out effect of MgSO4 and solventing-out effects of three different of alcohols, and the synergy of MgSO4 and alcohol on the solubilitiy of MnSO4.H2O. We have represented the three dimensional figures as a function of temperature.